The NFL’s Arizona Cardinals running back Jonathan Dwyer head-butted his wife and broke her nose after she refused his sexual advances, and punched her in the face the next day, police said today.

The details surfaced in a law enforcement report a day after Dwyer was arrested on aggravated assault charges and deactivated from all team activities after he was taken into custody at the Cardinals’ practice facility and headquarters in Tempe. He spent a night in jail and made a brief court appearance before being released on a $25,000 bond early this morning.

The arrest came at a time when the NFL and its commissioner are under fire over a series of violent off-the-field encounters involving some of the league’s marquee players, including Ray Rice, Adrian Peterson and Greg Hardy.